Wednesday, January 6, 2016

More Environmentally-Friendly Concrete Made Using Sugar Cane Residue

Date: January 4, 2016
Source: Asociación RUVID
Summary: A new type of concrete has been developed that is cheaper and much less polluting to the environment. Researchers have swapped in sugar cane straw ash, a crop residue typically discarded as waste, as a substitute for Portland cement.

Researchers from the Universitat Politècnica de València (Polytechnic University of Valencia, UPV) and San Paolo State University (Unesp) have developed a new type of concrete that is cheaper and much less polluting to the environment. They have done so by swapping in sugar cane straw ash, a crop residue typically discarded as waste, as a substitute for Portland cement.

Currently pursued at laboratory scale only, the results of this work have been published in the Construction and Building Materials journal. They also form part of Brazilian student João Cláudio Bassan de Moraes's master's dissertation, directed by lecturer Mauro Tashima, who completed his PhD at the UPV and is currently lecturing at Unesp.

Talking to us about the project, Jordi Payá, researcher at the Concrete Science and Technology Institute (ICITECH) at the UPV, explains: "The harvester strips the cane, discarding the tops and leaves as waste. This is the raw material we work with, sugar cane straw." In total around 650 million tonnes of sugar cane are harvested in Brazil every year. Of this, between 15 and 20% corresponds to sugar straw, which is left on the field and either burned or left to decay naturally.

So far, the international research team has been able to obtain concrete using 30% less Portland cement, substituting it with the ashes obtained from burning the sugar cane straw.

"The cement itself is the most expensive and most polluting ingredient of concrete, which makes the benefits [of this new method] as much economic as environmental. We are also making use of a by-product that is currently unexploited, with all the benefits that this entails" (Payá).

Process

To burn the waste, UPV and Unesp researchers have designed a bespoke combustion burner, into which the raw material must be fed following a strict procedure. "Through this process we obtain ashes that are very reactive to the cement, a quality that is very important to the mechanical performance of the resulting concrete, to its resistance to compression, for instance" (Payá).

Work has focused primarily on the microstructural analysis of the concrete. "In the lab we analyse the chemical compounds of the ashes and of the compounds produced during the reaction with the cement, in order to assess their performance in the final product," explains Payá. Future work would include studying indicators related to the durability of mass and reinforced concrete.

The ICITECH research team also studies the use of other agricultural waste as a cement substitute, including the bamboo leaf.


Story Source: The above post is reprinted from materials provided by Asociación RUVID.

Thursday, December 17, 2015

Our Water Pipes Crawl with Millions of Bacteria

Date: December 16, 2015

Source: Lund University

Summary: Our drinking water is to a large extent purified by millions of "good bacteria" found in water pipes and purification plants, Swedish researchers have found. So far, the knowledge about them has been practically non-existent, but this new research is about to change that.


A glass of water contains millions of bacteria, say researchers.
Credit: © Andrey Kuzmin / Fotolia

Researchers from Lund University in Sweden have discovered that our drinking water is to a large extent purified by millions of "good bacteria" found in water pipes and purification plants. So far, the knowledge about them has been practically non-existent, but this new research is about to change that.

A glass of clean drinking water actually contains ten million bacteria! But that is as it should be -- clean tap water always contains harmless bacteria. These bacteria and other microbes grow in the drinking water treatment plant and on the inside of our water pipes, which can be seen in the form of a thin, sticky coating -- a so-called biofilm. All surfaces from the raw water intake to the tap are covered in this biofilm.

Findings by researchers in Applied Microbiology and Water Resources Engineering show that the diversity of species of bacteria in water pipes is huge, and that bacteria may play a larger role than previously thought. Among other things, the researchers suspect that a large part of water purification takes place in the pipes and not only in water purification plants.

"A previously completely unknown ecosystem has revealed itself to us. Formerly, you could hardly see any bacteria at all and now, thanks to techniques such as massive DNA sequencing and flow cytometry, we suddenly see eighty thousand bacteria per millilitre in drinking water," says researcher Catherine Paul enthusiastically.

"From having been in the dark with a flashlight, we are now in a brightly lit room, but it is only one room. How many different rooms are in the house is also an interesting question!" she continues.

The work of doctoral student Katharina Lührig, who works together with Catherine, professors Peter Rådström and Kenneth Persson, and colleagues Björn Canbäck and Tomas Johansson has been published in Microbes and Environments.

The results have led to lively discussions within the industry about the role of biofilms in drinking water.

At least a couple of thousand different species live in the water pipes. According to the researchers there is a connection between the composition of bacteria and water quality.

"We suspect there are 'good' bacteria that help purify the water and keep it safe -- similar to what happens in our bodies. Our intestines are full of bacteria, and most the time when we are healthy, they help us digest our food and fight illness, says Catherine Paul.

Although the research was conducted in southern Sweden, bacteria and biofilms are found all over the world, in plumbing, taps and water pipes. This knowledge will be very useful for countries when updating and improving their water pipe systems.

"The hope is that we eventually may be able to control the composition and quality of water in the water supply to steer the growth of 'good' bacteria that can help purify the water even more efficiently than today," says Catherine Paul.


Story Source:
The above post is reprinted from materials provided by Lund University.

Tuesday, November 17, 2015

Bacteria, Graphene and Nanotech Produce Usable Electricity From Wastewater


Check out the kitchen timer counting down in the gif above. There’s nothing special about it except for how it is being powered. The instrument isn’t equipped with batteries. In fact, its electricity comes from the vial behind it, where bacteria are eating organic matter in wastewater and producing electricity as a result.

It’s the first time that researchers have produced enough electricity for practical use from what are called microbial fuel cells. Scientists in China reported their breakthrough late last week in the journal Science Advances. Their work could one day help provide the huge amounts of power needed to treat wastewater, a process that currently consumes up to 5 percent of all the electricity produced in the U.S.

For a while now, researchers have been investigating the bacterium Shewanella oneidensis, which naturally targets heavy metal ions and other pollutants in wastewater as a source of energy. The bacterium reduces these materials as a way to power its own metabolism, meanwhile converting them into less harmful derivatives. Engineers have figured out how to tap S. oneidensis’s to start harvesting the current for human use, but so far they haven’t been able to get enough out of the reaction because of technological limitations to do anything useful.

Shenlong Zhao and colleagues focused their work not on the bacterium, but on the material part of the battery that collects the electrons the microbe harvests. They worked out a better electrode made of a three-dimensional graphene aerogel decorated with platinum nanoparticles. The aerogel’s complex pores allows the microbe to colonize throughout it, maximizing the density of cells. The platinum nanoparticles, meanwhile, improve the material’s conductivity while also creating an environment more amenable to the organism’s survival.

The power output is enough for two of the vial-sized microbial fuel cells to power the kitchen timer. Meanwhile, tests with the fuel cells running on wastewater retrieved from a Beijing treatment plant indicated that real-world municipal wastewater could be used to produce electricity. Zhao’s team are now setting their sights on scaling up their preliminary work into larger applications.

Top gif: Digital photo of microbial fuel cells driving a timer. The two single biofuel cells have been assembled in series and successfully run a timer, strongly exemplifying that the graphene aerogel/platinum nanoparticle anode enables the superior performance and the actual application potential. Video and caption courtesy of Zhao et al./Science Advances.

Source: http://txchnologist.com/post/133351599065/bacteria-graphene-and-nanotech-produce-usable

Monday, November 9, 2015

Structure of 'Concrete Disease' Solved

Previously undocumented sheet-silicate crystal structure


Date: November 5, 2015
Source: Swiss Federal Laboratories for Materials Science and Technology (EMPA)
Summary: When bridges, dam walls and other structures made of concrete are streaked with dark cracks after a few decades, the culprit is AAR: the alkali-aggregate reaction. AAR damages concrete structures all over the world and makes complex renovations or reconstructions necessary. Researchers have now solved the structure of the material produced in the course of AAR at atomic Level.


Researchers from the Paul Scherrer Institute (PSI) teamed up with colleagues from the Swiss Materials Science Lab Empa to study a degenerative sign of ageing in concrete: the so-called alkali-aggregate reaction (AAR). In the course of AAR, a material forms that takes up more space than the original concrete and thus gradually cracks the concrete from within as the decades go by.

The researchers have now explored the exact structure of this material. They managed to demonstrate that its atoms are arranged extremely regularly, making it a crystal. They also showed that the structure of this crystal is a so-called sheet-silicate structure. This specific structure had never been observed before. The researchers made their discovery thanks to measurements at the Swiss Light Source SLS at PSI. The research results could help towards the development of more durable concrete in future.

A Global Problem

AAR is a chemical reaction that affects outdoor concrete structures all over the world. It happens when concrete is exposed to water or moisture. For instance, numerous bridges and up to twenty per cent of the dam walls in Switzerland are affected by AAR. With AAR, the basic ingredients in the concrete are actually the problem: cement -- the main component of concrete -- contains alkali metals such as sodium and potassium. Any moisture infiltrating the concrete -- stemming for example from rainwater -- reacts with these alkali metals, leading to an alkaline solution.

The second main ingredient in concrete is sand and gravel, which in turn are composed of minerals, such as quartz or feldspar. Chemically speaking, these minerals are so-called silicates. The alkaline water reacts with these silicates and forms a so-called alkali calcium silicate hydrate. This is itself able to absorb more moisture, which causes it to expand and gradually crack the concrete from within. This entire process is referred to as AAR.

AAR takes place extremely slowly, so that the cracks are initially only tiny and invisible to the naked eye. Over the course of three or four decades, however, the cracks widen significantly and eventually jeopardise the durability of the entire concrete structure.

A New Crystal

Even if the chemical processes involved in AAR have long been known, nobody had identified the physical structure of the alkali calcium silicate hydrate formed in the course of AAR. The researchers at PSI and Empa have now managed to fill this knowledge gap. They studied the substance of a Swiss bridge constructed in 1969, which has been affected heavily by AAR. Researchers from Empa cut out a material sample from the bridge and ground down a small piece of it until they were left with a wafer-thin sample that was merely 0.02 millimetres thick. The sample was then taken to the Swiss Light Source SLS and irradiated with an extremely narrow x-ray beam, fifty times thinner than a human hair. Performing so-called diffraction measurements and a complex data analysis, the PSI researchers were eventually able to determine the crystal structure of the material with pinpoint precision.

They found that the alkali calcium silicate hydrate has a previously undocumented sheet-silicate crystal structure. "Normally, discovering an uncatalogued crystal structure means you get to name it," explains Rainer Dähn, the first author of the study. "But it has to be a crystal found in nature, therefore we didn't get that honour," says the researcher with a smile. Andreas Leemann, Head of the Concrete Technology Group at Empa, had the idea for the current study. The researchers from PSI then brought their knowledge of the x-ray beam method to the table. "In principle, it's possible to add organic materials to the concrete that are able to reduce the build-up of tension," explains materials scientist Leemann. "Our new results provide a scientific basis for these considerations and could pave the way for the development of new materials.

Story Source: Swiss Federal Laboratories for Materials Science and Technology (EMPA). "Structure of 'concrete disease' solved: Previously undocumented sheet-silicate crystal structure." ScienceDaily. ScienceDaily, 5 November 2015. .

Friday, September 4, 2015

Wastewater to Irrigate, Fertilize and Generate Energy

Date: September 3, 2015
Source: Fraunhofer-Gesellschaft
Summary: To meet the requirements of Asian cities, researchers are adapting an idea they have already applied in Germany for comprehensive water management: developing a concept for reducing water use, treating wastewater and extracting fertilizer for a strip of coastline in the Vietnamese city of Da Nang


Agricultural areas in the Vietnamese city of Da Nang: in the future, residents can use purified wastewater to water their crops.
Credit: © Fraunhofer IGB

To meet the requirements of Asian cities, researchers are adapting an idea they have already applied in Germany for comprehensive water management: They are developing a concept for reducing water use, treating wastewater and extracting fertilizer for a strip of coastline in the Vietnamese city of Da Nang.

Urbanization is in full swing. Particularly in Asia, solutions are needed for feeding the growing population, supplying water and energy, and cleverly recycling waste wherever possible. In Vietnam, researchers from the Fraunhofer Institute for Interfacial Engineering and Biotechnology IGB in Stuttgart have adapted a wastewater treatment concept they developed in the DEUS 21 project to support the supply of water, energy and fertilizer.

Under the auspices of the German Society for International Cooperation GmbH (GIZ), the "Integrated Resource Management in Asian Cities: The Urban Nexus" project will now implement the innovative infrastructure along a strip of coastal land with some 200,000 residents in the Vietnamese city of Da Nang. Starting in the fall, 110 plots -- home to around 500 people -- are to be connected to a novel sewage network made up of vacuum pipes, which have a significantly smaller diameter than standard pipes. Wastewater is extracted with pumps, similar to the process used in trains and aircraft.

Until now, Da Nang's wastewater often flowed untreated into leaky ditches. Not only does this risk contaminating beaches, it also leaves untapped a valuable resource that the Fraunhofer researchers are now making accessible. Now for the first time, wastewater will be processed together with hotel kitchen waste; the resulting biogas will be used for cooking in hotel kitchens. Treated water will be used for urban agriculture -- meaning farmers will require less groundwater, reserves of which are at risk of becoming ever more saline as seawater is drawn in to replace the excessive volumes of freshwater being extracted during periods of drought. A further advantage is that nutrients found in the processed wastewater work as a natural fertilizer. So the novel system connects the pressing issues of supplying water, energy and food with little effort -- and the researchers achieve good results in each area. For example, with biogas: "At 45 liters per resident per day, our solution produces twice as much biogas as with traditional water treatment plants in Germany," says group manager Dr. Marius Mohr from the IGB.

Even the Wastewater Energy is Used


This concept sees wastewater purified biologically. "At the heart of the system are anaerobic bioreactors in which the organic component of wastewater ferments into biogas," Mohr explains. Bioreactors can also be combined with membrane filtration so that all larger particles, including the bacteria, remain inside the bioreactors. For cost reasons, this is not part of the initial plan for Da Nang.

The DEUS 21 concept was developed to maximize the recycling of wastewater and of the resources it contains. Not only can the biogas created in the anaerobic bioreactor be used for cooking, it can also be used to supply electricity and heat or to power vehicles. And because the wastewater remains relatively warm after processing, it is possible to draw additional thermal energy from it and supply this to households in cooler regions via a district heating network. "As another product of wastewater treatment nitrogen-phosphorus fertilizer can be won through a process of precipitation and ion exchange," Mohr explains.

The system could be implemented in many different regions, in particular where there is no sewer system or sewage treatment. "It's also suitable for export to areas with little water because it can be adapted to fit the needs of arid and semi-arid regions," Mohr adds.

Story Source:

The above post is reprinted from materials provided by Fraunhofer-Gesellschaft.

Fraunhofer-Gesellschaft. "Wastewater to irrigate, fertilize and generate energy." ScienceDaily. ScienceDaily, 3 September 2015. .

Tuesday, July 7, 2015

Crowd Computing to Improve Water Filtration

The research was conducted by 150,000 volunteers


Date: July 6, 2015
Source: American Friends of Tel Aviv University
Summary: Scientists propose a novel nanotechnology-based strategy to improve water filtration. The project was an experiment in crowdsourced computing -- carried out by over 150,000 volunteers who contributed their own computing power to the research.

Nearly 800 million people worldwide don't have access to safe drinking water, and some 2.5 billion people live in precariously unsanitary conditions, according to the Centers for Disease Control and Prevention. Together, unsafe drinking water and the inadequate supply of water for hygiene purposes contribute to almost 90% of all deaths from diarrheal diseases -- and effective water sanitation interventions are still challenging scientists and engineers.

A new study published in Nature Nanotechnology proposes a novel nanotechnology-based strategy to improve water filtration. The research project involves the minute vibrations of carbon nanotubes called "phonons," which greatly enhance the diffusion of water through sanitation filters. The project was the joint effort of a Tsinghua University-Tel Aviv University research team and was led by Prof. Quanshui Zheng of the Tsinghua Center for Nano and Micro Mechanics and Prof. Michael Urbakh of the TAU School of Chemistry, both of the TAU-Tsinghua XIN Center, in collaboration with Prof. Francois Grey of the University of Geneva.

Shake, Rattle, and Roll


"We've discovered that very small vibrations help materials, whether wet or dry, slide more smoothly past each other," said Prof. Urbakh. "Through phonon oscillations -- vibrations of water-carrying nanotubes -- water transport can be enhanced, and sanitation and desalination improved. Water filtration systems require a lot of energy due to friction at the nano-level. With these oscillations, however, we witnessed three times the efficiency of water transport, and, of course, a great deal of energy saved."

The research team managed to demonstrate how, under the right conditions, such vibrations produce a 300% improvement in the rate of water diffusion by using computers to simulate the flow of water molecules flowing through nanotubes. The results have important implications for desalination processes and energy conservation, e.g. improving the energy efficiency for desalination using reverse osmosis membranes with pores at the nanoscale level, or energy conservation, e.g. membranes with boron nitride nanotubes.

Crowdsourcing the Solution


The project, initiated by IBM's World Community Grid, was an experiment in crowdsourced computing -- carried out by over 150,000 volunteers who contributed their own computing power to the research.

"Our project won the privilege of using IBM's world community grid, an open platform of users from all around the world, to run our program and obtain precise results," said Prof. Urbakh. "This was the first project of this kind in Israel, and we could never have managed with just four students in the lab. We would have required the equivalent of nearly 40,000 years of processing power on a single computer. Instead we had the benefit of some 150,000 computing volunteers from all around the world, who downloaded and ran the project on their laptops and desktop computers.

"Crowdsourced computing is playing an increasingly major role in scientific breakthroughs," Prof. Urbakh continued. "As our research shows, the range of questions that can benefit from public participation is growing all the time."

The computer simulations were designed by Ming Ma, who graduated from Tsinghua University and is doing his postdoctoral research in Prof. Urbakh's group at TAU. Ming catalyzed the international collaboration. "The students from Tsinghua are remarkable. The project represents the very positive cooperation between the two universities, which is taking place at XIN and because of XIN," said Prof. Urbakh.

Other partners in this international project include researchers at the London Centre for Nanotechnology of University College London; the University of Geneva; the University of Sydney and Monash University in Australia; and the Xi'an Jiaotong University in China. The researchers are currently in discussions with companies interested in harnessing the oscillation know-how for various commercial projects.

Story Source: American Friends of Tel Aviv University. "Crowd computing to improve water filtration: The research was conducted by 150,000 volunteers." ScienceDaily. ScienceDaily, 6 July 2015. www.sciencedaily.com/releases/2015/07/150706123738.htm.

Tuesday, May 26, 2015

Climate Engineering May Save Coral Reefs, study shows

Date: May 25, 2015

Source: University of Exeter

Summary: Mass coral bleaching, which can lead to coral mortality, is predicted to occur far more frequently over the coming decades, due to the stress exerted by higher seawater temperatures. Geoengineering of the climate may be the only way to save coral reefs from mass bleaching, according to new research.


Current coral bleaching in Fiji.
Credit: Professor Peter J Mumby, University of Queensland

Geoengineering of the climate may be the only way to save coral reefs from mass bleaching, according to new research.


Coral reefs are considered one of the most vulnerable ecosystems to future climate change due to rising sea surface temperatures and ocean acidification, which is caused by higher atmospheric levels of carbon dioxide.

Mass coral bleaching, which can lead to coral mortality, is predicted to occur far more frequently over the coming decades, due to the stress exerted by higher seawater temperatures.

Scientists believe that, even under the most ambitious future CO2 reduction scenarios, widespread and severe coral bleaching and degradation will occur by the middle of this century.

The collaborative new research, which includes authors from the Carnegie Institution for Science, the University of Exeter, the Met Office Hadley Centre and the University of Queensland, suggest that a geoengineering technique called Solar Radiation Management (SRM) reduces the risk of global severe bleaching.

The SRM method involves injecting gas into the stratosphere, forming microscopic particles which reflect some of the sun's energy and so help limit rising sea surface temperatures.

The study compared a hypothetical SRM geoengineering scenario to the most aggressive future CO2 reduction strategy considered by the Intergovernmental Panel on Climate Change (IPCC), and found that coral reefs fared much better under geoengineering despite increasing ocean acidification.

The pioneering international study is published in leading scientific journal, Nature Climate Change.

Lead author Dr Lester Kwiatkowski of the Carnegie Institution for Science said "Our work highlights the sort of climate scenarios that now need to be considered if the protection of coral reefs is a priority."

Dr Paul Halloran, from the Geography department of the University of Exeter added: "The study shows that the benefit of SRM over a conventional CO2 reduction scenario is dependent on the sensitivity of future thermal bleaching thresholds to changes in seawater acidity.

This emphasises the need to better characterise how warming and ocean acidification may interact to influence coral bleaching over the 21st century."

Professor Peter Cox, co-author of the research and from the University of Exeter said: "Coral reefs face a dire situation regardless of how intensively society decarbonises the economy. In reality there is no direct choice between conventional mitigation and climate engineering but this study shows that we need to either accept that the loss of a large percentage of the world's reefs is inevitable or start thinking beyond conventional mitigation of CO2 emissions."

This work shows the very different impacts on coral bleaching of different measures to tackle climate change. These different techniques will also have different effects on other impacts such as regional crop growth or water availability.

Story Source: University of Exeter. "Climate engineering may save coral reefs, study shows." ScienceDaily. ScienceDaily, 25 May 2015. www.sciencedaily.com/releases/2015/05/150525120430.htm.