Tuesday, June 12, 2018

Wastewater Treatment Plants are Key Route into UK Rivers for Microplastics

Date: June 11, 2018
Source: University of Leeds
Summary: Water samples from UK rivers contained significantly higher concentrations of microplastics downstream from wastewater treatment plants, according to one of the first studies to determine potential sources of microplastics pollution.


Water samples from UK rivers contained significantly higher concentrations of microplastics downstream from wastewater treatment plants, according to one of the first studies to determine potential sources of microplastics pollution.

Scientists from the University of Leeds measured microplastics concentrations up and downstream of six wastewater treatment plants and found that all of the plants were linked to an increase in microplastics in the rivers -- on average up to three times higher but in one instance by a factor of 69.

Lead author Dr Paul Kay, from the School of Geography at Leeds, said: "Microplastics are one of the least studied groups of contaminants in river systems. These tiny plastic fragments and flakes may prove to be one of the biggest challenges in repairing the widespread environmental harm plastics have caused. Finding key entry points of microplastics, such as wastewater treatment plants, can provide focus points to combating their distribution.

"However, pervasive microplastics were also found in our upstream water samples. So while strengthening environmental procedures at treatment plants could be a big step in halting their spread, we cannot ignore the other ways microplastics are getting into our rivers."

Microplastics are pieces of plastic with a diameter less than five millimetres. They come from a wide range of materials including tiny plastic beads found in health and beauty products, plastic fibres from clothing and plastic flakes that break down from packaging.

In addition to exposing river ecosystems to the pollutants found in microplastics, a huge quantity continues to flow downstream and is then flushed into the ocean, posing a further threat to marine environments. Recent research has also found microplastics in fish stocks eaten by humans.

The researchers examined 28 river samples from six different field sites across Northern England. The treatment plants included in the study varied in the size of the population they served, the treatment technologies used and the river's characteristics. These variations allowed for a broader understanding of how different factors could affect how much wastewater treatment plants contribute to microplastic pollution.

In addition to treatment plants providing an entry point for microplastics found in both commercial and domestic wastewater, such as clothing and textile microfibers that shed into washing machines, wastewater treatment plants may also contribute secondary microplastics as a result of plastics caught in the treatment process breaking down further.

The study categorised the types of microplastics found, into pellets/beads, fibres and fragments/flakes. Fragment and fibres made up nearly 90% of the microplastics found in the river samples.

"By categorising the types of microplastics we can identify what aspects of our lifestyle are contributing to river pollution," said Dr Kay.

"Not that long ago microbeads in toiletries and cosmetics were the microplastics getting all the public attention. Seeing the amount of plastic microfibres from clothing and textiles polluting our rivers, we need to think seriously about the role of our synthetic fabrics in long-term environmental harm."

Story Source: University of Leeds. "Wastewater treatment plants are key route into UK rivers for microplastics." ScienceDaily. ScienceDaily, 11 June 2018. https://www.sciencedaily.com/releases/2018/06/180611133455.htm

Tuesday, June 5, 2018

Groundwater Pumping Can Increase Arsenic Levels in Irrigation and Drinking Water

Date: June 5, 2018
Source: Stanford University
Summary: Pumping an aquifer to the last drop squeezes out more than water. A new study finds it can also unlock dangerous arsenic from buried clays -- and reveals how sinking land can provide an early warning and measure of contamination.

For decades, intensive groundwater pumping has caused ground beneath California's San Joaquin Valley to sink, damaging infrastructure. Now research published in the journal Nature Communications suggests that as pumping makes the ground sink, it also unleashes an invisible threat to human health and food production: It allows arsenic to move into groundwater aquifers that supply drinking water for 1 million people and irrigation for crops in some of the nation's richest farmland.

The group found that satellite-derived measurements of ground sinking could predict arsenic concentrations in groundwater. This technique could be an early warning system to prevent dangerous levels of arsenic contamination in aquifers with certain characteristics worldwide.

"Arsenic in groundwater has been a problem for a really long time," said lead author Ryan Smith, a doctoral candidate in geophysics at the School of Earth, Energy & Environmental Sciences (Stanford Earth). It's naturally present in Earth's crust and a frequent concern in groundwater management because of its ubiquity and links to heart disease, diabetes, cancer and other illnesses. "But the idea that overpumping for irrigation could increase arsenic concentrations is new," Smith said.

Importantly, the group found signs that aquifers contaminated as a result of overpumping can recover if withdrawals stop. Areas that showed slower sinking compared to 15 years earlier also had lower arsenic levels. "Groundwater must have been largely turned over," said study co-author Scott Fendorf, a professor of Earth system science and a senior fellow at the Stanford Woods Institute for the Environment.

Releasing Arsenic from Clay

The research team analyzed arsenic data for hundreds of wells in two different drought periods alongside centimeter-level estimates of land subsidence, or sinking, captured by satellites. They found that when land in the San Joaquin Valley's Tulare basin sinks faster than 3 inches per year, the risk of finding hazardous arsenic levels in groundwater as much as triples.

Aquifers in the Tulare basin are made up of sand and gravel zones separated by thin layers of clay. The clay acts like a sponge, holding tight to water as well as arsenic soaked up from ancient river sediments. Unlike the sand and gravel layers, these clays contain relatively little oxygen, which creates conditions for arsenic to be in a form that dissolves easily in water.

When pumping draws too much water from the sand and gravel areas, the aquifer compresses and land sinks. "Sands and gravels that were being propped apart by water pressure are now starting to squeeze down on that sponge," Fendorf explained. Arsenic-rich water then starts to seep out and mix with water in the main aquifer.

When water pumping slows enough to put the brakes on subsidence -- and relieve the squeeze on trapped arsenic -- clean water soaking in from streams, rain and natural runoff at the surface can gradually flush the system clean.

However, study co-author Rosemary Knight, a professor of geophysics and affiliated faculty at the Woods Institute, warns against banking too much on a predictable recovery from overpumping. "How long it takes to recover is going to be highly variable and dependent upon so many factors," she said.

The researchers said overpumping in other aquifers could produce the same contamination issues seen in the San Joaquin Valley if they have three attributes: alternating layers of clay and sand; a source of arsenic; and relatively low oxygen content, which is common in aquifers located beneath thick clays.

The threat may be more widespread than once thought. Only in the last few years have scientists discovered that otherwise well-aerated aquifers considered largely immune to arsenic problems can in fact be laced with clays that have the low oxygen levels necessary for arsenic to move into most groundwater. "We're just starting to recognize that this is a danger," said Fendorf.

Satellite Insights

The revelation that remote sensing can raise an alarm before contamination threatens human health offers hope for better water monitoring. "Instead of having to drill wells and take water samples back to the lab, we have a satellite getting the data we need," said Knight.

While well data is important to validate and calibrate satellite data, she explained, on-the-ground monitoring can never match the breadth and speed of remote sensing. "You're never sampling a well frequently enough to catch that arsenic the moment it's in the well," said Knight. "So how fantastic to have this remote sensing early warning system to let people realize that they're approaching a critical point in terms of water quality."

The study builds on research led in 2013 by Laura Erban, then a doctoral student working in Vietnam's Mekong Delta. "That's where we started saying, 'Oh no,'" said Fendorf, who co-authored that paper.

As in the San Joaquin Valley, areas of the Mekong Delta where land was sinking more showed higher arsenic concentrations. "Now we have two sites in totally different geographic regions where the same mechanisms appear to be operating," said Fendorf. "That sends a trigger that we need to be thinking about managing groundwater and making sure that we're not overdrafting the aquifers."

Story Source:
Stanford University. "Groundwater pumping can increase arsenic levels in irrigation and drinking water." ScienceDaily. ScienceDaily, 5 June 2018.